LIFO (last in, first out) moves the most recently received items out first. It is the natural behaviour of a stack: you take what is on top. Like FIFO, the rule exists on two levels, physical handling and the accounting valuation of inventory.
Where LIFO makes physical sense
For bulk materials in piles (gravel, sand, de-icing salt, wood chips) or stacked pallets of one non-perishable product, reaching the oldest lot would cost more handling than it is worth. LIFO then simply reflects how the goods are stored. A custom WMS can apply LIFO to those zones and FIFO to the rest of the warehouse.
Why it is rare in accounting
When prices rise, LIFO pushes the recent (more expensive) purchases into the cost of sales, which lowers taxable profit and leaves old values sitting in inventory. That is why Canadian standards and IFRS do not allow it; it remains permitted in the United States.
Choosing the right rule
The question to ask: does the product change over time? If yes (expiry, versions, fashion), FIFO is required. If not and handling is the main cost, LIFO can be the operating rule while FIFO or average cost is kept for the books. A good inventory system lets you separate the physical rule from the accounting rule.